By Sébédio, Jean-Louis
Advances in Conjugated Linoleic Acid study, quantity 2 is the second one e-book in a sequence committed completely to conjugated linoleic acid. This e-book has up to date info at the research, biochemistry and functions of conjugated fatty acids in an try and make quantity 2, along side quantity 1 (published in 1999), the main entire, updated assets of CLA-related details to be had this day. either medical and advertisement perspectives are awarded, with an analogous facts occasionally interpreted another way
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P. (1997) Evaluating Acid and Base Catalysts in the Methylation of Milk and Rumen Fatty Acids with Special Emphasis on Conjugated Dienes and Total trans Fatty Acids, Lipids 32, 1219–1228. 51. -Y. (2000) Oxidative Stability of Conjugated Linoleic Acid Isomers, J. Agric. Food Chem. 48, 3072–3076. 52. L. (2001) Changes in Conjugated Linoleic Acid Composition Within Samples Obtained from a Single Source, Lipids 36, 315–317. 53. D. (1997) Isomers in Commercial Samples of Conjugated Linoleic Acid, Lipids 32, 1231.
The ions representing a particular positional isomer were assumed to be derived from the sum of the geometrical isomers. Indeed, the single double bond in the ring will always have cis geometry; consequently, the geometrical configurations of the original double bonds are completely lost. Reaney et al. (74) observed that c,t and t,t isomers gave MTAD adducts of different stereochemistry (trans and cis isomers of the chains about the ring, respectively), which were resolved by GC-MS on nonpolar columns (cis eluting first), although the mass spectra for any one positional isomer were indistinguishable.
All rights reserved. exchanged with silver (Ag) ions, is a useful technique for the separation and isolation of cis and trans geometric and positional FAME and TAG isomers. Ag-HPLC, utilizing columns packed with 5–10 µ Nucleosil SA (TM) (phenylsulfonic acid groups bonded to a silica substrate) or similar substrate in which the sulfonic acid protons have been exchanged with silver (Ag) ions (36), is a useful technique for the separation and isolation of cis and trans geometric and positional FAME and TAG isomers.
Advances in Conjugated Linoleic Acid Research by Sébédio, Jean-Louis